This couple will be somewhat made for each other. It may work out very well too, because the Aries male is ruled by Mars and the Libra female is ruled by Venus. These planets may be opposites but are attracted to each other and have the potential to open a new romantic chapter.
The dominant nature of a Libra female will rub the wrong way against other zodiac signs but an Aries man is probably one of the best matches for her risque nature. There is a possibility that his overriding nature may clash with hers but if it is well balanced then they might stick together and treat each others as equals. Another point where they are bound to clash is, over the non-stop adventurous nature of the Arian and the peace loving and equilibrium loving quality of the Libran female.
Both, the Aries male and Libra female have leadership qualities and like to take command over situations. Due to this very nature both will have occasional tiffs while making small or big decisions. Although, a Libra woman will appreciate the chivalrous and romantic nature shown by the Aries man.
The reality is that Arians are independent and like their space but will get exasperated and infuriated that the Librans will start influencing his decisions and vice a versa. This relationship will work wonders only if the Aries male and Libran female will start to cooperate and make decisions based on mutual understanding.
A Libra woman would like to be involved with an Aries man because of his adventurous nature and also because of his continuous search for excitement in life. A Libra woman will fall head over heels for a man if he is totally faithful and sticks to his word on commitment. These qualities and traits of an Aries man will keep a Libra woman interested in him and will result in escalation of romance.